Product ID:DISODIUM FLUORIDE, 6450
MSDS Date:11/17/1989
FSC:6850
NIIN:00N035991
MSDS Number: BQLNZ

EM SCIENCE

480 DEMOCRAT RD
GIBBSTOWN, NJ 08027
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 609-354-9200

Cage: DO242

EM SCIENCE

70 GIBBSTOWN, NJ 08927 US

Telephone: 800-424-9300 (CHEMTREC)

Cage: DO242

SODIUM FLUORIDE; (DISODIUM FLUORIDE) (SARA III) (PEL/TLV AS

CAS: 7681-49-4

RTECS: WB0350000

Fraction By Weight: 100%

OSHA PEL 2.5 MG/M3

ACGIH TLV: 2.5 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50: (ORAL,RAT) 52 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL & POSSIBLY FATAL IF INHALED OR
SWALLOWED. CAUSES EYE BURNS. CAUSES SEVERE IRRITATION ON CONTACT
WITH SKIN (MAY CAUSE BURNS). MAY CAUSE NAUSEA, VOMITING, ABDOMINAL
PAIN, STUPOR, WEAKNESS, TREMO RS, CONVULSION, COLLAPSE, RESPIRATORY
&CARDIAC FAILURE & DEATH. CHRONIC EFFECTS OF OVEREXP MAY INCL (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: MOTTLED TOOTH ENAMEL, CALCIUM
DEPOSITS, AND INCREASED BONE DENSITY. MAY CAUSE DAMAGE TO CNS,
RESPIRATORY SYSTEM AND KIDNEYS. TESTS ON LABORATORY ANIMALS
INDICATE MATERIAL MAY CAUSE TUMORS AN D PRODUCE ADVERSE MATAGENIC
AND REPRODUCTIVE EFFECTS.
Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE.

First Aid:GET MED ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: IMMED
FLUSH THOROUGHLY WITH LARGE AMOUNTS OF WATER. EYES: IMMED FLUSH
THORO WITH WATER FOR AT LEAST 15 MIN. INHAL: REMOVE TO FRESH AIR;
GIVE ART F RESP IF BREATHING HAS STOPPED. INGEST: DO NOT INDUCE
VOMITING; GET MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE.

Flash Point:NONCOMBUSTIBLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING MATERIALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HEAT MAY
EXPLODE.

Spill Release Procedures:EVAC AREA OF ALL UNNEC PERSONNEL. WEAR
SUITABLE PROT EQUIP LISTED UNDER EXPOS/PERSONAL PROT. ELIM ANY
IGNIT SOURCES UNTIL THE AREA IS DETERMINED TO BE FREE FROM
EXPLOSION/FIRE HAZ. CONTAIN THE RELEASE & ELIM ITS SOURCE, IF THIS
CAN BE DONE(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR CLOSED & PROT AGAINST
PHYSICAL DAMAGE. STORE IN A COOL, DRY, WELL-VENT AREA AWAY FROM
ACIDS AND ALKALIES.
Other Precautions:SODIUM FLUORIDE REACTS WITH ACIDS TO FORM HYDROGEN
FLUORIDE, WHICH IS HIGHLY CORROSIVE AND POISONOUS. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. HARMFUL & POSS FATAL IF
SWALLOWED/INHALED. CAUSES EYE BURNS. CAUSES SEVERE IRRIT (SUPP
DATA)

Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT(S) OF PROD OR ANY
COMPONENT IS EXCEEDED, A NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS
ADVISED IN ABSENCE OF PROPER ENVIRON CTRL. OSHA REGS ALSO PERMIT
OTHER NIOSH/MSHA APPRVD R ESP (NEGATIVE PRESS TYPE) (SUPP DATA)
Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME
HOOD OR WITH EQUIVALENT VENTILATION.
Protective Gloves:NEOPRENE OR EQUIVALENT.
Eye Protection:CHEM WORK GOGG & FULL LGTH FSHLD .
Other Protective Equipment:IMPERVIOUS PROT CLTHG SHLD BE WORN TO PVNT
SKIN CNTCT. EYEWASH & SFTY EQUIP SHOULD BE READILY AVAIL. DELUGE
SHOWER
Work Hygienic Practices:WASH THORO AFTER HANDLING. DO NOT TAKE
INTERNALLY.
Supplemental Safety and Health
SPILL PROC: WITHOUT RISK. TAKE UP AND CONTAINERIZE FOR PROPER DISP AS
DESCRIBED UNDER DISP. OTHER PREC: OR BURNS. MAY CAUSE DMG TO
KIDNEYS, NERV & RESP SYSTEMS. RESP PROT: UNDER SPECIFIED CNDTNS.
ENGI NEERING AND/OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED
TO REDUCE EXPOSURE.

HCC:T4
Boiling Pt:B.P. Text:3083F,1695C
Melt/Freeze Pt:M.P/F.P Text:1819F,993C
Vapor Density:1.4
Spec Gravity:2.78 (H*2O=1)
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE CRYSTALS OR POWDER; ODORLESS.

Stability Indicator/Materials to Avoid:YES
ACIDS, ALKALIES, GLASS.
Stability Condition to Avoid:HEAT.
Hazardous Decomposition Products:HYDROGEN FLUORIDE.

Waste Disposal Methods:COMPLY W/FEDERAL, STATE & LOCAL REGS ON
REPORTING RELEASES. REFER TO REGULATORY INFORMATION FOR REPORTABLE
QUANTITY AND OTHER REGULATORY DATA. ALWAYS CNTCT A PERMITTED WASTE
DISPOSER (TSD) TO ASSURE C OMPLIANCE W/ALL CURRENT LOC, STATE & FED
REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.